Gucci celebrated the launch of its Tattoo Heart Collection on Wednesday, a line of products that benefits UNICEF. Rihanna, who is the new face of the campaign, was joined Gucci creative director Frida Giannini at a snowflake lighting ceremony at the Grand Army Plaza, which was followed by an event at Gucci's flagship and dinner at the Plaza's Oak Room. Guests included Madonna, Penn Badgley, Blake Lively, Adrian Grenier, Monet Mazur, Timbaland, Mary J. Blige, Erin Wasson, Becki Newton and Chris Diamantopoulos, Kelly Rutherford, Patricia Field, Charlotte Ronson, Shoshanna Lonstein Gruss, Jessica Joffe, Julia Restoin Roitfeld, Mamie Gummer, Eleanor Ylvisaker, Bethenny Frankel, Anja Rubik, Hal Rubenstein, Magnus Berger, Joe Zee, Kelly Killoren Bensimon, Lizzie and Jonathan Tisch, and Maggie Betts. [Style.com, NYO, PMc, Wireimage]